Journal
GREEN CHEMISTRY
Volume 16, Issue 3, Pages 1077-1081Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3gc41658e
Keywords
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Funding
- National Natural Science Foundation of China [21072047, 21172059, 21272059, 21202039, 21372066]
- Excellent Youth Foundation of Henan Scientific Committee [114100510012]
- Program for Innovative Research Team from the University of Henan Province [2012IRTSTHN006]
- Program for Changjiang Scholars and Innovative Research Team in University [IRT1061]
- Research Fund for the Doctoral Program of Higher Education of China [20124104110006]
- Program for Science & Technology Innovation Talents in Universities of Henan Province [13HASTIT013]
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A simple dehydrazination reaction has been achieved in the presence of a catalytic amount of CuSO4 for the first time. With CuSO4 (2 mol%) as a catalyst and water as a solvent, the dehydrazination products were obtained in good yields (66-95%). Moreover, the drugs nebularine and vidarabine were afforded successfully, and vidarabine could be produced on a 0.923 kg scale, which shows good potential for industrial applications.
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