Journal
GREEN CHEMISTRY
Volume 16, Issue 6, Pages 3013-3017Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3gc42624f
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Funding
- National Science Council, Republic of China
- Academia Sinica
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Copper-catalyzed alkene oxidation to carbonyl compounds by tert-butyl hydroperoxide (TBHP) under organic solvent-free and biphasic conditions at room temperature is selective for the aromatic gem-disubstituted alkenes. Enhanced reactivity was observed in the presence of 2,9-dimethyl-1,10-phenanthroline (neocuproine). The reaction is economically attractive because the yield is high, and separation of products and recycling of the catalyst are easy.
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