4.8 Article

A simple metal-free catalytic sulfoxidation under visible light and air

Journal

GREEN CHEMISTRY
Volume 15, Issue 2, Pages 357-361

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2gc36683e

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Funding

  1. NSFC [21102097]
  2. Specialized Research Fund for the Doctoral Program of Higher Education [20103201120006]
  3. Beijing National Laboratory for Molecular Sciences (BNLMS)
  4. Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD)

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A metal-free aerobic selective sulfoxidation photosensitized by Rose Bengal or solid-supported Rose Bengal has been developed. The reaction utilizes visible light as the driving force and molecular oxygen as the oxidant. Among the advantages of the developed method are its high efficiency and selectivity, extremely simple operation and workup procedure, and minimal waste generation.

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