4.8 Article

Iodine-catalyzed efficient 2-arylsulfanylphenol formation from thiols and cyclohexanones

Journal

GREEN CHEMISTRY
Volume 15, Issue 12, Pages 3302-3306

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3gc41671b

Keywords

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Funding

  1. National Natural Science Foundation of China [21172185, 21372187]
  2. Hunan Provincial Natural Science Foundation of China [11JJ1003, 12JJ7002]
  3. Research Fund for the Doctoral Program of Higher Education of China
  4. Ministry of Education of China [20124301110005]
  5. Research Fund for the Education Department of Hunan Province of China [13C192]

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A novel method for the formation of 2-arylsulfanylphenols from thiols and cyclohexanones is described. Iodine was used as an effective catalyst for this kind of transformation. Cyclohexanones were used as a phenol source via a dehydrogenation and tautomerization reaction.

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