Journal
GREEN CHEMISTRY
Volume 15, Issue 10, Pages 2690-2694Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3gc41024b
Keywords
-
Funding
- National Science Foundation [CHE-1213287]
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [1213287] Funding Source: National Science Foundation
Ask authors/readers for more resources
Diarylprolinol silyl ether-based organocatalyst 2, in conjunction with ionic liquid supported (ILS) sulfonic acid 6a as co-catalyst, leads to a novel organocatalyst in aqueous media. The in situ generated catalyst demonstrated high reactivity and stereoselectivity for the Michael reactions of linear aldehydes to maleimides in brine without any organic solvents. For these reactions, up to 76% yield, 9:1 dr and 96% ee were obtained for a broad variety of aldehydes and maleimides.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available