Journal
GREEN CHEMISTRY
Volume 15, Issue 12, Pages 3360-3366Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3gc41384e
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Funding
- National Research Council (CONICET)
- National Agency for the Promotion of Science and Technology (ANPCyT)
- National University of Mar del Plata (UNMdP)
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Epoxidised soybean oil (ESO) was cross-linked with an aqueous citric acid (CA) solution without the addition of any other catalyst or solvent. Completely bio-based polymer networks were generated. The initial system was an emulsion, but it became a homogeneous and transparent polymer network by reaction. The ability of the final materials to self-heal without adding extrinsic catalysts was assessed by stress relaxation and lap-shear tests. This was achieved by molecular rearrangements produced by thermally activated transesterification reactions of beta-hydroxyester groups generated in the polymerization reaction.
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