Journal
GREEN CHEMISTRY
Volume 15, Issue 9, Pages 2389-2393Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3gc40658j
Keywords
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Funding
- 973 Program [2011CBA00506]
- National Natural Science Foundation of China
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The gas-phase hydrogenation of dimethyl 1,4-cyclohexane dicarboxylate to 1,4-cyclohexane dimethanol was performed on a well-dispersed Cr-free supported copper-based catalyst derived from a Cu-Mg-Al layered double hydroxide precursor, and achieved a lasting 100% conversion with 99.8% selectivity up to 200 hours. The unprecedented catalytic performance is ascribed to the synergistic effect between surface active Cu-0 sites and Lewis base sites.
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