4.8 Article

On the ethenolysis of end-of-life tire granulates

Journal

GREEN CHEMISTRY
Volume 15, Issue 2, Pages 315-319

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2gc36417d

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Funding

  1. DFG [Pl 178/13-1]

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End-of-life tire granulates were used in olefin metathesis reactions with ethene (ethenolysis); utilizing 0.0074 mmol of a Grubbs type ruthenium complex for 1.0 gram of tire granules leads to the isolation of ca. 0.5 g of organic solubles, which are primarily composed of oligomeric 1,4-cis isoprenes.

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