4.8 Article

A one-pot approach for conversion of fructose to 2,5-diformylfuran by combination of Fe3O4-SBA-SO3H and K-OMS-2

Journal

GREEN CHEMISTRY
Volume 14, Issue 11, Pages 2986-2989

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2gc35947b

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Funding

  1. National Basic Research Program of China (973 program) [2012CB215305, 2012CB215306]
  2. National Natural Science Foundation of China [21172209]
  3. Chinese Academy of Science [KJCX2-EW-J02]

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We have demonstrated an efficient, selective and environmentally benign heterogeneous catalyst (K-OMS-2) for aerobic oxidation of 5-HMF to 2,5-DFF. In addition, a combination of Fe3O4-SBA-SO3H and K-OMS-2 successfully catalyzed direct synthesis of 2,5-DFF from fructose via acid-catalyzed dehydration and successive aerobic oxidation in one-pot reaction.

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