4.8 Article

Solvent isotope effect and mechanism for the production of hydrogen and lactic acid from glycerol under hydrothermal alkaline conditions

Journal

GREEN CHEMISTRY
Volume 14, Issue 12, Pages 3285-3288

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2gc36153a

Keywords

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Funding

  1. National Natural Science Foundation of China [21006074, 20976139, 51138009]
  2. National Key Technology R&D Program of China [2012BAJ25B02]
  3. Research and Development Project of Ministry of Housing and Urban-Rural Development [2011-K7-70]
  4. Foundation of State Key Laboratory of Pollution Control and Resources Reuse of China [PCRRF11010]
  5. Fundamental Research Funds for the Central Universities [2870219011]
  6. National Sparking Plan Project [2010GA680011]

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To discover the reaction mechanism for the production of hydrogen and lactic acid from glycerol under alkaline hydrothermal conditions, we identified the different intermediates involved during reactions by investigating the solvent isotope effect with H-1-NMR, H-2-NMR, LC-MS and Gas-MS analyses, and then proposed and proved a potential reaction mechanism.

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