Journal
GREEN CHEMISTRY
Volume 14, Issue 12, Pages 3429-3435Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2gc36379h
Keywords
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Funding
- National Natural Science Foundation of China [20972042, 21172057]
- PCSIRT [IRT1061]
- RFDP [20114104110005]
- [2012IRTSTHN006]
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In this paper, a catalyst-free synthesis of diversely substituted 6H-benzo[c]chromenes and 6H-benzo[c]chromen-8-ols via cascade reactions of 2-(2-(allyloxy) phenyl) furan and 2-(2-(prop-2-ynyloxy) phenyl)furan, featured with intramolecular Diels-Alder reactions of furan with unactivated alkene/alkyne in aqueous media under MWI, was developed. In addition, an environmentally friendly oxidation of 6H-benzo[c]chromenes into the corresponding benzo[c]chromen-6-ones using aqueous H2O2 as an oxidant, in the absence of any activator/catalyst, was also revealed.
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