Journal
GREEN CHEMISTRY
Volume 14, Issue 4, Pages 925-929Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2gc16679h
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Funding
- Newcastle University
- EPSRC
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A linear cation-decorated polymeric support with tuneable surface properties and microstructure has been prepared by ring-opening metathesis polymerisation (ROMP) of a pyrrolidinium-functionalised norbornene-based monomer with cyclooctene. The derived peroxophosphotungstate-based polymer-immobilised ionic liquid phase (PIILP) catalyst is an efficient and recyclable system for the epoxidation of allylic alcohols and alkenes, with only a minor reduction in performance on successive cycles.
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