Journal
GREEN CHEMISTRY
Volume 13, Issue 3, Pages 562-565Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0gc00848f
Keywords
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Funding
- NSFC [20902010]
- State Key Laboratory of Bio-organic and Natural Products Chemistry, Key Laboratory of Natural Resources of Changbai Mountain & Functional Molecules (Yanbian University)
- Jilin Provincial Natural Science Foundation [20101537]
- Young Scientific Research Foundation of Jilin Province [20090138]
- Science Foundation for Young Teachers of Northeast Normal University [09QNJJ013]
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Cu2O as the catalyst in water was found to be quite robust for the azide-alkyne cycloaddition (AAC) reaction, which was verified by a wide variety of applicable azides and alkynes. Water was proved to play an essential role because of a significant rate acceleration compared with reactions using organic solvents and conducted under neat conditions. The high catalytic performance of Cu2O/H2O system was further argued by decreasing the catalyst loading to ppm levels.
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