Journal
GREEN CHEMISTRY
Volume 13, Issue 2, Pages 266-271Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0gc00686f
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Funding
- Total Petrochemicals Co.
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A simple isocyanate-free method to synthesize poly( trimethylene carbonate hydroxy-urethane)s is described. The strategy first involves the synthesis of alpha,omega-di(cyclic carbonate) telechelic polycarbonate precursors upon ring-opening polymerization of trimethylene carbonate using a cyclic carbonate alcohol as chain transfer agent, followed by the ring-opening polyaddition of the terminal cyclic carbonate with a diamine. Such poly(carbonate-hydroxyurethane) s exhibit macromolecular carbonate segments of tunable length/molar mass.
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