4.8 Article

Selective conversion of glycerol to 1,3-propanediol using Pt-sulfated zirconia

Journal

GREEN CHEMISTRY
Volume 13, Issue 8, Pages 2004-2007

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c1gc15263g

Keywords

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Funding

  1. Ministry of Education, Science and Technology [2010-0009174]
  2. Korean Ministry of Environment [202-091-001]
  3. DAPA/ADD of Korea
  4. Korea Environmental Industry & Technology Institute (KEITI) [0920112000200010] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
  5. National Research Foundation of Korea [2010-0009174, 과C6A1905] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)

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Pt-deposited sulfated zirconia was used as a catalyst for the selective hydrogenolysis of glycerol to 1,3-propanediol. The Bronsted acid sites on the catalyst, which were promoted by hydrogen spillover on platinum, were more advantageous for producing 1,3-propanediol than 1,2-propanediol.

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