4.8 Article

Clean and rapid synthesis of double metal cyanide complexes using mechanochemistry

Journal

GREEN CHEMISTRY
Volume 13, Issue 10, Pages 2701-2703

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c1gc15557a

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Funding

  1. Key Scientific and Technical Project of Hainan Province [090502]
  2. Project of Scientific and Technical Personnel Server for Enterprises [2009GJE20014]

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A novel and green chemistry technique is presented for the synthesis of double metal cyanide (DMC) complexes that are further used for the copolymerization of CO2 and propylene oxide. The catalytic activity and selectivity are improved by this strikingly efficient and practically applicable method. The mechanosynthesis of DMC reveals clear merits.

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