Journal
GREEN CHEMISTRY
Volume 13, Issue 5, Pages 1187-1195Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1gc15048k
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Funding
- EC [PITN-GA-2008-215193, CP-FP 211468-2]
- DAAD
- Royal Society
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Continuous flow homogeneous alkene metathesis using a supported ionic liquid phase (SILP) catalyst with CO2 as a transport vector allows the self-metathesis of methyl oleate with only a slight loss of activity for at least 10 h; cross-metathesis of dimethyl maleate with methyl oleate ceases after 3 h, but the catalyst remains active for methyl oleate metathesis. The reasons for this unusual behaviour are explored and a practical system for the cross-metathesis of methyl oleate with dimethyl maleate, under batch conditions, is described.
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