Journal
GREEN CHEMISTRY
Volume 13, Issue 4, Pages 843-846Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1gc15106a
Keywords
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Funding
- Chubu Bureau of Economy Trade and Industry
- [B21390030]
- [22106515]
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Solkane (R) 365 mfc is proven to be an environmentally benign alternative solvent for the homocoupling reaction of terminal alkynes catalyzed by CuCl/TMEDA under air at room temperature. A variety of terminal alkynes, including aromatic, heteroaromatic and aliphatic alkynes, were cleanly transformed into 1,3-diynes within a short period in high to excellent yields up to 98%.
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