Journal
GREEN CHEMISTRY
Volume 12, Issue 11, Pages 2030-2037Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0gc00118j
Keywords
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Funding
- National Natural Science Foundation of China [20806002, 20976005]
- Beijing Natural Science Foundation [2103051]
- PetroChina Innovation Foundation [2010D-5006-0403]
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Four low-viscosity ionic liquids (ILs) based on the dicyanamide anion ([N(CN)(2)]), i.e., 1-butyl-3-methylimdazolium ([BMI][N(CN)(2)]), 1-ethyl-3-methylimdazolium ([EMI][N(CN)(2)]), ethylated tetrahydrothiophenium ([S2][N(CN)(2)]) and ethyldimethylsulfonium ([EtMe2S][N(CN)(2)]), have been investigated to determine their extraction capability for thiophene (TS) and dibenzothiophene (DBT) from model fuel oils. Aromatic imidazolium is more efficient than cyclic thiophenium and tetrahedral trialkylsulfonium; specifically, the S-extraction ability follows the order [BMI][N(CN)(2)] > [EMI][N(CN)(2)] > [S2][N(CN)(2)] > [EtMe2S][N(CN)(2)], with DBT being more efficiently extracted than TS. The S-extraction of [BMI][N(CN)(2)] has been investigated as a representative with respect to the influence of extraction temperature, IL: oil mass ratio, initial S-content, multiple extractions and reusability, along with its mutual solubility in oil. The percentage of S-removal from gasoline and diesel fuel were 48.5 and 68.7%, respectively, in a single extraction at 25 degrees C, 1 : 1(w/w) IL : oil, 5 min; the S-content in gasoline decreased from 599 ppm to 4 ppm after 5 extraction cycles and in diesel fuel decreased from 606 ppm to an undetectable value after 4 cycles. The mutual solubility is not pronounced and the extraction efficiency is not conspicuously changed after 6 regeneration cycles. It is worth noting that a short extraction time of < 5 min is observed for all the ILs at room temperature, which is understood by their low viscosities and effective mass transfer. This work may offer a new option for the deep desulfurization of fuel oils.
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