Journal
GREEN CHEMISTRY
Volume 11, Issue 6, Pages 816-820Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b813019a
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Funding
- Consorzio di Ricerca per l'Innovazione Tecnologica, la Qualita e la Sicurezza degli Alimenti S.C.R.L., L'Aquila, Italy [20.12.04, DM 28497]
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A new catalytic aerobic oxidation of alcohols to aldehydes under green conditions was developed (room temperature and pressure, water solution, open vials). The water-soluble platinum(II) tetrasulfophthalocyanine (PtPcS) catalyst showed the best selectivity for carbonyl derivatives, and in particular for alpha,beta-unsaturated alcohols; the reactions are slow.
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