4.8 Article

A green and efficient oxidation of alcohols by supported gold catalysts using aqueous H2O2 under organic solvent-free conditions

Journal

GREEN CHEMISTRY
Volume 11, Issue 6, Pages 756-759

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/b820197h

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Funding

  1. National Natural Science Foundation of China [20633030, 20721063, 20873026]
  2. National Basic Research Program of China [2003CB 615807]
  3. Shanghai Education Committee [06SG03]
  4. Science & Technology Commission of Shanghai Municipality [08DZ2270500, 07QH14003]

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The use of supported gold nanoparticles as an efficient, green and reusable catalyst for the oxidation of various alcohols to the corresponding carbonyl compounds using aqueous hydrogen peroxide as an environmentally benign oxidant is presented. The reaction proceeds with good to excellent yields in particular for nonactivated alcohols under base-free conditions.

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