Journal
GREEN CHEMISTRY
Volume 11, Issue 11, Pages 1815-1820Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b916767f
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Funding
- MEC/MICINN of Spain [CTQ2006-04204/BQU]
- Consolider Ingenio 2010 [CSD2007-00006]
- Generalitat de Catalunya [SGR2005-00305, SGR 2009-1441]
- CNANO
- CNRS
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Organic-inorganic hybrid silica materials containing imidazolium and dihydroimidazolium salts prepared from monosilylated and disilylated monomers by sol-gel methodologies are active and reusable organocatalysts for the Knoevenagel condensation of aromatic aldehydes with malononitrile and ethyl cyanoacetate under solvent-free conditions. Our immobilized systems present higher activities than related homogeneous bis-imidazolium salts, showing the cooperative effect of the matrix surface and the additional advantage of easy recycling. The best performances were obtained with the material derived from polycondensation of a disilylated dihydroimidazolium salt in the absence of tetraethoxysilane (TEOS).
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