Journal
GREEN CHEMISTRY
Volume 11, Issue 6, Pages 767-769Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b822822a
Keywords
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Funding
- National Natural Science Foundation of China [20532010]
- Chinese Academy of Sciences [KJCX2.YW.H16]
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The phosphine-free chiral cationic Ru(OTf)(TsDPEN)(eta(6)-cymene) complex was found to be an efficient catalyst for the enantioselective hydrogenation of quinolines under more environmentally friendly solvent-free or highly concentrated conditions. Excellent yields and enantioselectivities (up to 97%ee) were obtained at only 0.02-0.10 mol% catalyst loading.
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