Journal
GREEN CHEMISTRY
Volume 11, Issue 7, Pages 911-920Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b820740b
Keywords
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Funding
- University of Massachusetts Boston Center
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Described in this paper is a personal overview of the green chemistry aspects of fluorous technologies. The unique phase separation and broad combinatorial capabilities of fluorous technologies have led to the development of fluorous chromatography-free separations, chemical recycling techniques, atom economic reactions, energy-focused microwave reactions, metal-free organocatalysis, aqueous media reactions, and modified reagents. These green chemistry techniques have been demonstrated in discovery chemistry, medicinal chemistry, and academic research labs dealing with small-scale organic synthesis. Issues such as the environmental impact of fluorous chemicals are also discussed.
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