Journal
GREEN CHEMISTRY
Volume 10, Issue 3, Pages 271-274Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b719493e
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The performance of two commercially available olefin metathesis catalysts in water has been studied. Ultrasonication of the water-insoluble substrates and catalysts in water allowed the formation of stable emulsions without added surfactants, while the smooth catalytic metathesis took place in the water-insoluble emulsion droplets. Ring-closing (RCM), enyne and cross metathesis (CM) of a variety of substrates proceed with remarkable efficiency in water using acoustic emulsification.
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