3.9 Article

Mixed alkali-zinc diphosphates: Synthesis, structure, and properties

Journal

GLASS PHYSICS AND CHEMISTRY
Volume 38, Issue 6, Pages 491-503

Publisher

PLEIADES PUBLISHING INC
DOI: 10.1134/S108765961206003X

Keywords

alkali-zinc diphosphates; synthesis; properties; structure

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A series of mixed alkali-zinc diphosphates in the form of poly- and single crystals have been synthesized. Their physical-chemical, structural, and thermal characteristics have been determined. The compounds Na2ZnP2O7 and K2ZnP2O7 have a layered structural type, whereas LiNaZnP2O7, LiKZnP2O7, NaKZnP2O7, Li12Zn4(P2O7)(5), and K2Zn3(P2O7)(2) have a framework structural type.

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