Growing season methyl bromide and methyl chloride fluxes at a sub-arctic wetland in Sweden

Methyl bromide and methyl chloride fluxes were measured at several sites in a sub-arctic wetland near Abisko, Sweden (68 degrees 28'N 18 degrees 49'E) throughout the 2008 growing season. Averaged over 92 flux measurements the sub-arctic wetland was found to be a small net sink for CH(3)Br, with mean (+/-1 sd) uptake of -25 (+/-20) ng m(-2) h(-1), but a small net source of CH(3)Cl with mean emissions of 400 (+/-1600) ng m(-2) h(-1). Seasonal trends were observed in both CH(3)Br and CH(3)Cl net fluxes, but diurnal trends for CH(3)Cl only, with peak emissions observed during the afternoon. CH(3)Cl fluxes differed significantly with hydrological status of measurement locations; however, no other substantial correlations were observed between fluxes and external parameters (air and soil temperature and PAR). This study shows that the single previous estimated sink flux for CH(3)Cl in tundra globally (derived from measurements in Alaska) requires revision, although not that for CH(3)Br. Citation: Hardacre, C. J., E. Blei, and M. R. Heal (2009), Growing season methyl bromide and methyl chloride fluxes at a sub-arctic wetland in Sweden, Geophys. Res. Lett., 36, L12401, doi:10.1029/2009GL038277.