Reaction of zero-valent magnesium with water: Potential applications in environmental remediation

This study examined the dissolution kinetics of granular zero-valent Mg (ZVMg) at pH 7 in water that was open to the atmosphere and buffered with 50 mM Na-MOPS. The oxidative dissolution of ZVMg was rapid; the initial amount of ZVMg (10-50 mg/L) dissolved completely within 200 min. The rate and extent of ZVMg dissolution was not affected by atmospheric oxygen. Although the oxidation of ZVMg is thermodynamically more feasible by dissolved oxygen or proton ions (H+), the primary oxidants are water molecules. The initial rate of ZVMg dissolution obeys first order kinetics with respect to ZVMg concentration with an observed rate constant, k(Mg,7) = 1.05 +/- 0.06 x 10(-2) min(-1). Model calculations using the rate constant perfectly predict the extent of ZVMg dissolution for an extended time period at lower [Mg-0](0) but underestimate at 50 mg/L [Mg-0](0). The offset is likely attributed to the rapid dissolution of ZVMg particles, which could cause a substantial increase in the specific surface area. As to the reactivity of Mg-water system, we suggest that the hydrated electron (e(aq)(-)), the most powerful reducing agent, would probably be the major reactive entity under neutral and alkaline conditions. In addition, we discuss briefly the factors affecting the rate and extent of the Mg-water reaction such as background electrolytes, ZVMg impurities, surface passivation, solution pH and temperature based on literature review. (C) 2012 Elsevier Ltd. All rights reserved.