Coordination of Cd2+ ions in the internal pore system of zeolite-X: A combined EXAFS and isotopic exchange study

The effect of prolonged contact time (up to 130 days) on the immobilization of Cd by sorption to calcium exchanged zeolite-X (CaX), under environmentally relevant conditions, was studied using both isotopic exchange and extended X-ray absorption fine structure spectroscopy (EXAFS). Sorption and isotopic exchange measurements revealed time-dependent Cd sorption and indicated the movement of Cd2+ ions into less accessible sites due to ageing. EXAFS suggested progressive fixation of Cd in the double six-ring (D6R) unit of the CaX structure. Proportional allocation of the apparent Cd-Si bond distance to two 'end-members', across all contact times, indicated that the bond distance for labile Cd was 3.41 angstrom and for non-labile (or fixed) Cd was 3.47 angstrom. (C) 2009 Elsevier Ltd. All rights reserved.