Neutron irradiation effects on optical absorption of KU1 and KS-4V quartz glasses and Infrasil 301

In this work we have compared the effects of neutron (10(21)-10(22) n/m(2) fluences) and gamma irradiation (23.8 MGy dose) on the IR-vis-UV optical absorption spectra of high purity silica with different OH content: KU1 (similar to 800 ppm). KS-4V (<0.2 ppm), and commercial silica Infrasil 301 (<8 ppm). The results show that the UV-vis optical degradation of the silica, after neutron irradiation at the highest fluence is similar for the three grades studied, while gamma-induced optical absorption depends on the material grade (KS-4V shows the lowest optical absorption). The effects of both types of radiation on the IR band related with the hydroxyl group (3650 cm(-1)) depend on the silica grade. For KU1, the shape of this band changes with neutron fluence. For Infrasil 301 gamma and neutron irradiated, this band height increases, possibly due to free molecular or hydrogen atoms. The shift to lower energies observed for the 2260 cm(-1) band in the three neutron irradiated silica grades, reflects the changes induced by neutrons in the lattice bonding angle distribution. (C) 2008 Elsevier B.V. All rights reserved.