4.3 Article

Carbon nanoflakes as a promising anode for sodium-ion batteries

Journal

FUNCTIONAL MATERIALS LETTERS
Volume 11, Issue 6, Pages -

Publisher

WORLD SCIENTIFIC PUBL CO PTE LTD
DOI: 10.1142/S1793604718400118

Keywords

Carbon nanoflake; sodium-ion batteries; anode, seudocapacitive behavior

Funding

  1. National Natural Science Foundation of China [51672182, 51772197, 51872192]
  2. Thousand Young Talents Plan
  3. Jiangsu Natural Science Foundation [BK20180002, BK20151219]
  4. Key University Science Research Project of Jiangsu Province [17KJA430013]
  5. 333 High-Level Talents Project in Jiangsu Province
  6. Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD)
  7. Russian Science Foundation [18-13-00217]

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The sharp increase in the cost of lithium resource has driven the research on sodium-ion batteries (SIBs) as sodium shares a similar electrochemical property as lithium. Carbonaceous materials are important anodes for rechargeable batteries, but the prevailing graphite only shows a limited activity towards sodium storage. Herein, we demonstrate that carbon nanoflakes serve as an efficient anode material for SIBs, exhibiting a stable capacity of 148 mAh g(-1) over 600 continuous cycles at 150 mA g(-1) and an excellent rate capability of 120 mAh g(-1) at 1500 mA g(-1). More importantly, sodium storage in carbon nanoflakes exhibits a pseudocapacitive behavior, possibly due to their larger interlayer spacing and less-ordered structure vs. crystallized carbon.

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