4.3 Article Proceedings Paper

TEM MICROSTRUCTURE ANALYSIS FOR COMPRESSIVELY STRESSED Pb(Zr,Ti)O3 THIN FILMS BY CSD-DERIVED LaNiO3 BOTTOM ELECTRODES

Journal

FUNCTIONAL MATERIALS LETTERS
Volume 5, Issue 2, Pages -

Publisher

WORLD SCIENTIFIC PUBL CO PTE LTD
DOI: 10.1142/S1793604712600168

Keywords

CSD; thin film; PZT; stress; TEM

Funding

  1. Grants-in-Aid for Scientific Research [23656397, 23360283] Funding Source: KAKEN

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Pb(Zr,Ti)O-3 (PZT) possesses superior ferroelectric and piezoelectric properties arisen near a morphotropic phase boundary (MPB) composition, PbZr0.53Ti0.47O3. We have prepared a PZT (MPB composition) thin film and perovskite-type LaNiO3 (LNO) electrodes on Si substrate by chemical solution deposition (CSD) method. The CSD-derived LNO bottom electrode applied compressive stress to the PZT film and enhanced the ferroelectric properties of the PZT film. TEM and SAED revealed that stress distribution and microstructures of the PZT/LNO/Si films effectively influenced the ferroelectric properties.

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