Journal
FUEL PROCESSING TECHNOLOGY
Volume 95, Issue -, Pages 90-95Publisher
ELSEVIER
DOI: 10.1016/j.fuproc.2011.11.023
Keywords
Montmorillonite; Adsorption; SO2; Combustion
Funding
- Polish Ministry of Science and Higher Education
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A series of montmorillonites with adsorbed nickel ions was prepared through adsorption of nitrates from water solutions; there were four methods adopted. The surface of the sample under modification was investigated with the method of argon adsorption and XPS (X-ray photoelectron spectroscopy). SO2 was investigated on nickel-modified montmorillonites. Nickel cations were adsorbed on the montmorillonite surface as Ni2+ in Ni(OH)(2) or NiO. Montmorillonite - after nickel adsorption - adsorbs SO2 physically. An addition of Mont-Ni to hard coal in a ratio 1:500 reduces SO2 emissions in the combustion process by 75-85%. Waste bentonite can be utilized for reducing SO2 emissions after processing. (C) 2011 Elsevier B.V. All rights reserved.
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