Journal
FOOD RESEARCH INTERNATIONAL
Volume 43, Issue 5, Pages 1517-1522Publisher
ELSEVIER
DOI: 10.1016/j.foodres.2010.04.033
Keywords
Acrylamide; Stability; Mitigation; Condensation products; Cysteine; Michael addition
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Funding
- Research Foundation - Flanders (Belgium) (FWO-Vlaanderen)
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Since the discovery of relatively high amounts of the carcinogenic acrylamide in heat-processed food products, many studies have been devoted to the formation of acrylamide. However, as acrylamide is an alpha,beta-unsaturated amide, subsequent reactions can provoke the desired removal of this compound. Therefore, the stability of acrylamide and its reactivity with various food-relevant nucleophiles were studied. The results showed that acrylamide was quite stable in aqueous solutions, but much less in dry reaction conditions. Buffer type and pH had a significant influence on the decrease of free acrylamide. The presence of amino acids with a nucleophilic side chain considerably decreased the free acrylamide, due to Michael-type addition reactions. The highest reactivity was noted for cysteine, leading to the formation of the mono-addition product cysteine-S-beta-propionamide, as well as to the double addition product. Other nucleophiles, such as lysine, arginine, serine and ascorbic acid, were less reactive, but yielded comparable condensation products. (C) 2010 Elsevier Ltd. All rights reserved.
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