Journal
ACS NANO
Volume 9, Issue 10, Pages 10252-10257Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acsnano.5b04185
Keywords
stretchable conductor; few-walled carbon nanotube; PMIA; core/shell structure; fibers; stretching-induced alignment
Categories
Funding
- NSF [EECS-1344745, CHE-1213469]
- Duke University SMIF (Shared Materials Instrumentation Facilities)
- China Scholarship Council
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A core/shell stretchable conductive composite of a few-walled carbon nanotube network coated on a poly(m-phenylene isophthalamide) fiber (FWNT/PMIA) was fabricated by a dip-coating method and an annealing process that greatly enhanced interactions between the FWNT network and PMIA core as well as within the FWNT network. The first strain conductivity test of the as-prepared FWNT/PMIA fiber showed a stretching-induced alignment of nanotubes in the shell during the deformation process and a good conductivity stability with a slight conductivity drop from 109.63 S/cm to 98.74 5/cm (Delta sigma/sigma(0) = 10%) at a strain of similar to 150% (2.5 times the original length). More importantly, after the first stretching process, the fiber can be recovered with a slight increase in length but a greatly improved conductivity of 167.41 S/cm through an additional annealing treatment. The recovered fiber displays a similarly superb conductivity stability against stretching, with a decrease of only similar to 13 S/cm to 154.49 S/cm (Delta sigma/sigma(0) = 8%) at a strain of similar to 150%. We believe that this conductivity stability came from the formation and maintaining of aligned nanotube structures during the stretching process, which ensures the good tube tube contacts and the elongation of the FWNT network without losing its conductivity. Such stable conductivity in stretchable fibers will be important for applications in stretchable electronics.
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