4.2 Article Proceedings Paper

The Dice-Stone Der Wurfelstein: Some Personal Souvenirs Around the Discovery of the First Ferromagnetic Ferroelectric

Journal

FERROELECTRICS
Volume 427, Issue -, Pages 1-33

Publisher

TAYLOR & FRANCIS LTD
DOI: 10.1080/00150193.2012.673896

Keywords

Multiferroic; ferroelastic; ferroelectric; ferromagnetic; ferrotoroidic; boracites

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Historical flashlights are presented on the real life background of the discovery in 1964 of the first ferromagnetic/ferroelectric single crystalline material, Nickel Iodine Boracite. The subsequent stony trail until support for scientific follow-up, finally obtained in 1978, is summarised. Leaving out intermediate research milestones, the present day state-of-the-art is succinctly resumed, culminating in the insight that a variety of boracite phases are ferroelastic, ferroelectric, ferromagnetic and ferrotoroidic in the same phase, representing herewith useful model substances for studying a high degree of multiferroic complexity.

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