Journal
FARADAY DISCUSSIONS
Volume 154, Issue -, Pages 145-153Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1fd00054c
Keywords
-
Categories
Funding
- EPSRC
- DFG
- EPSRC [EP/F06926X/1, EP/J004790/1, EP/E046541/1] Funding Source: UKRI
- Engineering and Physical Sciences Research Council [EP/J004790/1, EP/F06926X/1, EP/E046541/1] Funding Source: researchfish
Ask authors/readers for more resources
The structure and dynamics of ionic liquids (ILs) are unusual due to the strong interactions between the ions and counter ions. These microscopic properties determine the bulk transport properties critical to applications of ILs such as advanced fuel cells. The terahertz dynamics and slower relaxations of simple alkylammonium nitrate protic ionic liquids (PILs) are here studied using femtosecond optical Kerr-effect spectroscopy, dielectric relaxation spectroscopy, and terahertz time-domain spectroscopy. The observed dynamics give insight into more general liquid behaviour while comparison with glass-forming liquids reveals an underlying power-law decay and relaxation rates suggest supramolecular structure and nanoscale segregation.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available