Journal
JOURNAL OF THE ELECTROCHEMICAL SOCIETY
Volume 162, Issue 4, Pages A531-A537Publisher
ELECTROCHEMICAL SOC INC
DOI: 10.1149/2.0141504jes
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Funding
- Copenhagen Cleantech Cluster
- Danish Council for Independent Research
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In commercial Fe-based batteries the Fe2+/Fe3+ oxidation states are used, however by also utilizing the Fe4+ oxidation state, intercalation of up to two Li ions per Fe ion could be possible. In this study, we investigate whether Fe4+ can be formed and stabilized in beta-Li3Fe2(PO4)(3). The work includes in situ synchrotron X-ray powder diffraction studies (XRPD) during charging of beta-Li3Fe2(PO4)(3) up to 5.0 V vs. Li/Li+. A novel capillary-based micro battery cell for in situ XRPD has been designed for this. During charge, a plateau at 4.5 V was found and a small contraction in volume was observed, indicating some Li ion extraction. The volume change of the rhombohedral unit cell is anisotropic, with a decrease in the a parameter and an increase in the c parameter during the Li ion extraction. Unfortunately, no increased discharge capacity was observed and Mossbauer spectroscopy showed no evidence of Fe4+ formation. Oxidation of the organic electrolyte is inevitable at 4.5 V but this alone cannot explain the volume change. Instead, a reversible oxygen redox process (O2--> O-) could possibly explain and charge compensate for the reversible extraction of lithium ions from beta-Li3Fe2(PO4)(3). (C) 2015 The Electrochemical Society. All rights reserved.
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