Journal
EUROPEAN POLYMER JOURNAL
Volume 47, Issue 5, Pages 882-892Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.eurpolymj.2011.02.001
Keywords
Electrospinning; Alignment; Packing; Epitaxial; Hollow fiber; Membrane
Categories
Funding
- National Science Council, Taiwan [NSC96-2221-E-038-002]
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Novel epitaxial-like packed, super aligned, mono-layered hollow fibrous membranes were prepared by co-axial electrospinning technology. PLLA pellets were dissolved in solvent mixture of dichloromethane and dimethyl formamide (DCM/DMF = 9:1) to prepare sheath solution dope with various concentrations (from 8 to 19 wt.%). Aqueous solution of polyethylene glycol (PEG) was used as core solution dope. During the electrospinning process, dope concentrations and feed rate ratios were adjusted, separately, to evaluate the formation of resulting membranes. With lower shell solution concentration (from 8 to 15 wt.%), the collected, flattened film showed arrangement of lower order. A stood-up film was clearly seen when concentration increased to 17 wt.% and higher. As the collecting time went longer, these fibers piled up and eventually, stood up as a thin film from the surface of collector. Increasing flow rate ratio (FRR) also resulted similar outcomes and verify the cause of this phenomenon. After washing with water, scanning electron microscopy (SEM) revealed sheets of mono-layered, micron-sized hollow fiber arrays which were well aligned and tightly packed, just like the epitaxial growth of some semiconducting materials. These perfectly aligned and tightly packed hollow fiber arrays can be considered as highly anisotropic scaffolds that mimic tissue structures, such as nerve tissue, vascular structure as well as other application. (C) 2011 Elsevier Ltd. All rights reserved.
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