Journal
EUROPEAN POLYMER JOURNAL
Volume 44, Issue 11, Pages 3835-3841Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.eurpolymj.2008.07.052
Keywords
Atom transfer radical polymerization; Block copolymers; Controlled polymerization; Self-assembly
Categories
Funding
- NSF China [50473056, 20534010, 20625412]
- MOST [G2003CB615605]
Ask authors/readers for more resources
ATRP of a gelable monomer, 3-(triethoxysilyl)propyl methacrylate (TESPMA), mediated by CuBr/N,N,N',N '',N ''-pentamethyldiethylenetriamine (PMDETA) using ethyl 2-bromoisobutyrate (2-EBiB) as initiator was studied. The results indicate that polymerization follows the first-order kinetic. PolyTESPMA (PTESPMA) is much more stable to moisture which is important for exploring the properties of its block copolymer. A series of PEO-b-PTESPMA block copolymers with different composition were prepared. Self-assembly of PEO-b-PTESPMA has also been explored in a mixture of methanol and water and polymeric vesicles have been obtained. By introducing the gelation catalyst, the block copolymer vesicles can be stabilized by the silica networks. (c) 2008 Elsevier Ltd. All rights reserved.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available