4.3 Article

Biaxial nematic phase in the Maier-Saupe model for a mixture of discs and cylinders

Journal

EUROPEAN PHYSICAL JOURNAL E
Volume 35, Issue 2, Pages -

Publisher

SPRINGER
DOI: 10.1140/epje/i2012-12014-1

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Funding

  1. FAPESP
  2. CNPq

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We analyze the global phase diagram of a Maier-Saupe lattice model with the inclusion of shape-disordered degrees of freedom to mimic a mixture of oblate and prolate molecules (discs and cylinders). In the neighborhood of a Landau multicritical point, solutions of the statistical problem can be written as a Landau-de Gennes expansion for the free energy. If the shape-disordered degrees of freedom are quenched, we confirm the existence of a biaxial nematic structure. If orientational and disorder degrees of freedom are allowed to thermalize, this biaxial solution becomes thermodynamically unstable. Also, we use a two-temperature formalism to mimic the presence of two distinct relaxation times, and show that a slight departure from complete thermalization is enough to stabilize a biaxial nematic phase.

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