4.8 Article

Ni-Catalyzed Borylation of Aryl Fluorides via C-F Cleavage

Journal

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 137, Issue 39, Pages 12470-12473

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/jacs.5b08103

Keywords

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Funding

  1. ICIQ
  2. European Research Council [ERC-277883]
  3. MINECO [CTQ2012-34054]
  4. Cellex Foundation
  5. MINECO for FPU scholarship
  6. MINECO (Severo Ochoa Excellence Accreditation) [SEV-2013-0319]
  7. ICREA Funding Source: Custom

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A Ni-catalyzed borylation via C-F activation is described. This protocol is distinguished by a wide scope, including unactivated fluoroarenes, without compromising its efficiency and scalability, thus representing a significant step-forward toward the implementation of C-F activation protocols.

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