Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 137, Issue 45, Pages 14313-14318Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jacs.5b10119
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Funding
- JSPS KAKENHI Grant [15K05509]
- Incentive Research Grant from RIKEN
- Grants-in-Aid for Scientific Research [15K05509] Funding Source: KAKEN
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Ni/Cu-catalyzed transformation of fluroarenes to arylboronic acid pinacol esters via C-F bond cleavage has been achieved. Further versatile derivatization of an arylboronic ester has allowed for the facile two-step conversion of a fluoroarene to diverse functionalized arenes, demonstrating the synthetic utility of the method.
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