Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 137, Issue 50, Pages 15636-15639Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jacs.5b10593
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Funding
- Marie Curie Foundation
- European Research Council
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The first methodology for Au(I/III)-catalyzed oxidative cross-coupling of arenes via double C-H activation has been developed. The reaction is fully selective for the cross-coupling between electron-rich hetero-/carbocyclic arenes and electron-poor arenes bearing relatively acidic C-H bonds: The inherently high cross-selectivity of the system obviates the need for directing groups or a large excess of one of the coupling partners.
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