Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 137, Issue 36, Pages 11610-11613Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jacs.5b07432
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Funding
- European Research Council (ERC) [307948]
- Swiss National Science Foundation [200020_146853]
- Novartis Post-Doctoral program
- Swiss National Science Foundation (SNF) [200020_146853] Funding Source: Swiss National Science Foundation (SNF)
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A Pd-catalyzed three component reaction involving terminal alkynes, boronic acids, and perfluoralkyl iodides is presented here. Trisubstituted perfluoro-alkenes can be obtained in a highly regio- and stereocontrolled manner by the simultaneous addition of both aryl and CnFm groups across the triple bond in a radical-mediated process. The reaction is operationally simple offering a broad scope and functional group tolerance.
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