4.8 Article

Interface Tension-Induced Synthesis of Monodispersed Mesoporous Carbon Hemispheres

Journal

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 137, Issue 8, Pages 2808-2811

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/jacs.5b01522

Keywords

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Funding

  1. Key Basic Research Program [2013CB934104, 2012CB224805]
  2. NSFC [21210004, 21322311]
  3. Shanghai Foundation of S T Project [14JC1400700]

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Here we report a novel interface tension-induced shrinkage approach to realize the synthesis of monodispersed asymmetrical mesoporous carbon nanohemispheres. We demonstrate that the products exhibit very uniform hemispherical morphology (130 x 60 nm) and are full of ordered mesopores, endowing them high surface areas and uniform pore sizes. These monodispersed mesoporous carbon hemispheres display excellent dispersibility in water for a long period without any aggregation. Moreover, a brand new feature of the mesoporous carbon materials has been observed for the first time: these monodispersed mesoporous carbon hemispheres show excellent thermal generation property under a NIR irradiation.

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