4.8 Article

Selective Synthesis of Ruthenium(II) Metalla[2]Catenane via Solvent and Guest-Dependent Self-Assembly

Journal

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 137, Issue 14, Pages 4674-4677

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/jacs.5b02573

Keywords

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Funding

  1. National Research Foundation of Korea (NRF) - Ministry of Science, ICT, and Future Planning [NRF-2013R1A1A2006859]
  2. Ministry of Education [NRF-2014R1A1A2007828, NRF-2014R1A1A2007897]
  3. Priority Research Centers Program through the NRF [2009-0093818]
  4. Research and Development Project of ICIER [B5-2513]
  5. National Research Council of Science & Technology (NST), Republic of Korea [KIER8-1] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
  6. National Research Foundation of Korea [2014R1A1A2007897, 22A20130000138, 2009-0093818, 2014R1A1A2007828, 2013R1A1A2006859] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)

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The coordination-driven self-assembly of an anthracene-functionalized ditopic pyridyl donor and a tetracene-based dinuclear Ru(II) acceptor resulted in an interlocked metalla[2]catenane, [M2L2](2), in methanol and a corresponding monorectangle, [M2L2], in nitromethane. Subsequently, guest template, solvent, and concentration effects allowed the self-assembly to be reversibly fine-tuned among monorectangle and catenane structures.

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