Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 137, Issue 19, Pages 6164-6167Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jacs.5b02897
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Funding
- U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences [DE-SC0006937]
- NSF under the MRSEC Program [DMR-08-19762]
- Sloan Foundation
- Research Corporation for Science Advancement
- 3M
- EPSRC [EP/L00202]
- European Research Council [277757]
- EPSRC [EP/L000202/1] Funding Source: UKRI
- Engineering and Physical Sciences Research Council [EP/L000202/1] Funding Source: researchfish
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Reaction of FeCl2 and H4DSBDC (2,5-disulfhydrylbenzene-1,4-dicarboxylic acid) leads to the formation of Fe-2(DSBDC), an analogue of M-2(DOBDC) (MOE-74, DOBDC4- = 2,5-dihydroxybenzene-1,4-dicarboxylate), The bulk electrical conductivity values of both Fe-2(DSBDC) and Fe-2(DOBDC) are similar to 6 orders of magnitude higher than those of the Mn2+ analogues, Mn-2(DEBDC) (E = O, S). Because the metals are of the same formal oxidation state, the increase in conductivity is attributed to the loosely bound Fe2+ beta-spin electron. These results provide important insight for the rational design of conductive metal-organic frameworks, highlighting in particular the advantages of iron for synthesizing Such materials.
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