Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 137, Issue 34, Pages 10962-10964Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jacs.5b07415
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Funding
- Ministry of Education, Culture, Sports, Science and Technology (MEXT), Japan
- Kanazawa University CHOZEN Project
- JSPS KAKENHI [15H00990]
- Grants-in-Aid for Scientific Research [15H00990] Funding Source: KAKEN
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Pillar[5]arene-based multilayer films are constructed by layer-by-layer assembly with consecutive adsorption of cationic and anionic pillar[5]arenes. The films have active pores that allow shape-selective uptake of dinitrobenzene isomers: the film adsorbs para-dinitrobenzene, but not ortho- and meta-dinitrobenzene. The ability of the film to adsorb para-dinitrobenzene is result of the surface electrostatic potential: para-dinitrobenzene adsorbs on films with a positive surface, but not on films with a negative surface. The adsorbed amount of para-dinitrobenzene exponentially increases with increasing number of deposited layers.
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