4.8 Article

Oxalates as Activating Groups for Alcohols in Visible Light Photoredox Catalysis: Formation of Quaternary Centers by Redox-Neutral Fragment Coupling

Journal

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 137, Issue 35, Pages 11270-11273

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/jacs.5b07678

Keywords

-

Funding

  1. NSF [CHE1265964]
  2. NIHGMS [R01-GM098601, R01-GM078201]
  3. Direct For Mathematical & Physical Scien
  4. Division Of Chemistry [1265964] Funding Source: National Science Foundation

Ask authors/readers for more resources

Alkyl oxalates are new bench-stable alcohol-activating groups for radical generation under visible light photoredox conditions. Using these precursors, the first net redox-neutral coupling of tertiary and secondary alcohols with electron-deficient alkenes is achieved.

Authors

I am an author on this paper
Click your name to claim this paper and add it to your profile.

Reviews

Primary Rating

4.8
Not enough ratings

Secondary Ratings

Novelty
-
Significance
-
Scientific rigor
-
Rate this paper

Recommended

No Data Available
No Data Available